Coordination chemistry of surface-grafted ligands for antibacterial materials

Pallavicini, Piersandro, Dacarro, Giacomo, Diaz-Fernandez, Yuri Antonio and Taglietti, Angelo (2014) Coordination chemistry of surface-grafted ligands for antibacterial materials. COORDINATION CHEMISTRY REVIEWS, 275. pp. 37-53.

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Abstract

Antibacterial metal complex monolayers covalently grafted on bulk surfaces are reviewed, focusing on the experimental values found for metal:ligand surface stoichiometry, on the surface concentration of the complexes, on time-regulated cation release and on the relation with the observed antibacterial properties. Stability, geometry and coordination features of the surface-grafted complexes are discussed where available, and compared with the classical ligand/metal behavior found in solution. In the applicable cases, comparison is made also with surfaces bearing monolayers of silver nanoparticles as antibacterial agents, evidencing the advantages of the coordination complex monolayers in obtaining fast release, efficient antibacterial action and null or negligible risks as regards toxicity. © 2014 Elsevier B.V.

Item Type:	Article
Uncontrolled Keywords:	Surface grafting, Self-assembled monolayer, Antibacterial material, Copper complex, Silver complex
Subjects:	?? QD ?? ?? QR ??
Depositing User:	Symplectic Admin
Date Deposited:	20 Jul 2015 09:31
Last Modified:	16 Dec 2022 01:53
DOI:	10.1016/j.ccr.2014.04.013
Related URLs:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/2016903