Karabach, Yauhen Y, Kopylovich, Maximilian N, Luzyanin, Konstantin V ORCID: 0000-0001-9312-7139, Guedes da Silva, M Fatima C, Kukushkin, Vadim Yu and Pombeiro, Armando JL
(2017)
Expanding the family of substituted-at-core nickel(II) phthalocyanines.
INORGANICA CHIMICA ACTA, 455.
pp. 696-700.
Text
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Abstract
A series of soluble in common organic solvents nickel(II) 14,28-dialkoxy-substituted phthalocyanines is synthesized by reaction of nickel acetate tetrahydrate with 1,2-dicyanobenzene in the presence of an alcohol under solvothermal conditions. Single crystal X-ray diffraction analyses reveal that the two alkoxy groups are added in a syn-conformation mode in all the studied cases. The use of microwave irradiation leads to decomposition of the nickel(II) 14,28-dialkoxy-substituted phthalocyanines.
Item Type: | Article |
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Uncontrolled Keywords: | Nickel(II) complexes, Phthalocyanines, Solvothermal synthesis, Microwave-assisted reaction |
Depositing User: | Symplectic Admin |
Date Deposited: | 19 Aug 2016 08:16 |
Last Modified: | 19 Jan 2023 07:32 |
DOI: | 10.1016/j.ica.2016.04.015 |
Related URLs: | |
URI: | https://livrepository.liverpool.ac.uk/id/eprint/3002976 |