Sprick, Reiner Sebastian, Bonillo, Baltasar, Clowes, Rob, Guiglion, Pierre, Brownbill, Nick J, Slater, Benjamin J, Blanc, Frederic 
ORCID: 0000-0001-9171-1454, Zwijnenburg, Martijn A, Adams, Dave J and Cooper, Andrew I ORCID: 0000-0003-0201-1021
(2016)
Visible‐Light‐Driven Hydrogen Evolution Using Planarized Conjugated Polymer Photocatalysts.
Angewandte Chemie International Edition, 55 (5).
pp. 1792-1796.
This is the latest version of this item.
![[img]](https://livrepository.liverpool.ac.uk/style/images/fileicons/text.png) |
Text
201506773_revised.docx - Unspecified Access to this file is embargoed until Unspecified. Download (1MB) |
|
Text
Sprick_et_al-2016-Angewandte_Chemie_International_Edition.pdf - Published version Download (916kB) |
![[img]](https://livrepository.liverpool.ac.uk/style/images/fileicons/application_atom+xml.png) |
Atom XML (admin)
2017-05-12T11:18:47Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-12T12:17:49Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-12T13:17:17Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-12T14:17:07Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-12T15:17:20Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-12T16:17:26Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-12T17:17:11Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-12T18:17:36Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-12T19:17:22Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-12T20:17:25Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-12T21:17:40Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-12T22:18:21Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-12T23:22:54Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-13T01:18:25Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-13T02:18:01Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-13T03:18:12Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-13T04:32:44Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-13T05:17:55Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-13T06:17:20Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-13T07:17:45Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-13T08:17:59Z.atom - Unspecified Download (0B) |
|
Atom XML (admin)
2017-05-13T09:17:23Z.atom - Unspecified Download (0B) |
Abstract
Linear poly(p‐phenylene)s are modestly active UV photocatalysts for hydrogen production in the presence of a sacrificial electron donor. Introduction of planarized fluorene, carbazole, dibenzo[b,d]thiophene or dibenzo[b,d]thiophene sulfone units greatly enhances the H2 evolution rate. The most active dibenzo[b,d]thiophene sulfone co‐polymer has a UV photocatalytic activity that rivals TiO2, but is much more active under visible light. The dibenzo[b,d]thiophene sulfone co‐polymer has an apparent quantum yield of 2.3 % at 420 nm, as compared to 0.1 % for platinized commercial pristine carbon nitride.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | conjugated polymer, extended conjugation, photocatalysis, planarization, water splitting |
| Depositing User: | Symplectic Admin |
| Date Deposited: | 09 Feb 2017 16:35 |
| Last Modified: | 19 Jan 2023 07:19 |
| DOI: | 10.1002/anie.201510542 |
| Related URLs: | |
| URI: | https://livrepository.liverpool.ac.uk/id/eprint/3005636 |
Available Versions of this Item
-
Visible-Light-Driven Hydrogen Evolution Using Planarized Conjugated Polymer Photocatalysts. (deposited 19 Aug 2016 08:46)
- Visible‐Light‐Driven Hydrogen Evolution Using Planarized Conjugated Polymer Photocatalysts. (deposited 09 Feb 2017 16:35) [Currently Displayed]
Dimensions
Dimensions
