Walsh, James J, Neri, Gaia ORCID: 0000-0003-1326-9327, Smith, Charlotte L and Cowan, Alexander J ORCID: 0000-0001-9032-3548
(2014)
Electrocatalytic CO<sub>2</sub> reduction with a membrane supported manganese catalyst in aqueous solution.
CHEMICAL COMMUNICATIONS, 50 (84).
pp. 12698-12701.
Text
Mn-bpy_aa.docx - Author Accepted Manuscript Download (2MB) |
Abstract
[Mn(bpy)(CO)3Br] cast in a Nafion membrane is an active heterogeneous electrocatalyst with good selectivity for CO2 reduction to CO in neutral aqueous electrolyte. Addition of multi-walled carbon nanotubes (MWCNT) leads to a ∼10 fold current enhancement and stable CO : H2 yields (1 : 2) at -1.4 V vs. Ag/AgCl at pH 7.
Item Type: | Article |
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Depositing User: | Symplectic Admin |
Date Deposited: | 10 Feb 2017 10:12 |
Last Modified: | 18 Oct 2023 07:01 |
DOI: | 10.1039/c4cc06404f |
Related URLs: | |
URI: | https://livrepository.liverpool.ac.uk/id/eprint/3005706 |