Electrocatalytic CO<sub>2</sub> reduction with a membrane supported manganese catalyst in aqueous solution



Walsh, James J, Neri, Gaia ORCID: 0000-0003-1326-9327, Smith, Charlotte L and Cowan, Alexander J ORCID: 0000-0001-9032-3548
(2014) Electrocatalytic CO<sub>2</sub> reduction with a membrane supported manganese catalyst in aqueous solution. CHEMICAL COMMUNICATIONS, 50 (84). pp. 12698-12701.

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Abstract

[Mn(bpy)(CO)3Br] cast in a Nafion membrane is an active heterogeneous electrocatalyst with good selectivity for CO2 reduction to CO in neutral aqueous electrolyte. Addition of multi-walled carbon nanotubes (MWCNT) leads to a ∼10 fold current enhancement and stable CO : H2 yields (1 : 2) at -1.4 V vs. Ag/AgCl at pH 7.

Item Type: Article
Depositing User: Symplectic Admin
Date Deposited: 10 Feb 2017 10:12
Last Modified: 18 Oct 2023 07:01
DOI: 10.1039/c4cc06404f
Related URLs:
URI: https://livrepository.liverpool.ac.uk/id/eprint/3005706