Barday, Manuel, Janot, Christopher, Clare, Daniel, Carr-Knox, Caitlin, Higginson, Bradley, Ho, Kelvin YT and Aissa, Christophe ORCID: 0000-0003-0750-9435
(2017)
On the Regioselectivity of the Nickel-Catalyzed Insertion of Alkynes into the Carbon-Carbon Bond of Oxetan-3-one.
SYNTHESIS-STUTTGART, 49 (16).
pp. 3582-3589.
Text
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Abstract
<jats:p>The study of the regioselectivity of insertion of unsymmetrical alkynes into the carbon–carbon bond of oxetan-3-one in the presence of a nickel catalyst has revealed a strong directing effect of a 2-thienyl substituent. This effect is larger than those of 2-vinylbenzene, trimethylsilyl, aryl, or 3-thienyl groups.</jats:p>
Item Type: | Article |
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Uncontrolled Keywords: | carbon-carbon bond activation, nickel, catalysis, oxeta-none, alkynes, regioselectivity, insertion, pyrans |
Depositing User: | Symplectic Admin |
Date Deposited: | 29 Jun 2017 08:34 |
Last Modified: | 19 Jan 2023 07:02 |
DOI: | 10.1055/s-0036-1589052 |
Related URLs: | |
URI: | https://livrepository.liverpool.ac.uk/id/eprint/3008170 |