Possible Fano resonance for high-T<sub>c</sub> multi-gap superconductivity in p-Terphenyl doped by K at the Lifshitz transition



Mazziotti, Maria Vittoria, Valletta, Antonio, Campi, Gaetano, Innocenti, Davide ORCID: 0000-0002-0465-3039, Perali, Andrea and Bianconi, Antonio
(2017) Possible Fano resonance for high-T<sub>c</sub> multi-gap superconductivity in p-Terphenyl doped by K at the Lifshitz transition. EPL, 118 (3). p. 37003.

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Abstract

Recent experiments have reported the emergence of high-temperature superconductivity with critical temperature Tc between 43 K and 123 K in a potassium-doped aromatic hydrocarbon para-Terphenyl or p-Terphenyl. This achievement provides the record for the highest Tc in an organic superconductor overcoming the previous record of Tc = 38 K in Cs3C60 fulleride. Here we propose that the driving mechanism is the quantum resonance between superconducting gaps near a Lifshitz transition which belongs to the class of Fano resonances called shape resonances. For the case of p-Terphenyl our numerical solutions of the multigap equation shows that high Tc is driven by tuning the chemical potential by K doping and it appears only in a narrow energy range near a Lifshitz transition. At the maximum critical temperature, Tc = 123 K, the condensate in the appearing new small Fermi surface pocket is in the BCS-BEC crossover while the Tc drops below 0.3 K where it is in the BEC regime. Finally, we predict the experimental results which can support or falsify our proposed mechanism: a) the variation of the isotope coefficient as a function of the critical temperature and b) the variation of the gaps and their ratios 2Δ/Tc as a function of Tc.

Item Type: Article
Depositing User: Symplectic Admin
Date Deposited: 01 Aug 2017 06:21
Last Modified: 12 Oct 2023 17:52
DOI: 10.1209/0295-5075/118/37003
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URI: https://livrepository.liverpool.ac.uk/id/eprint/3008747