Ribeiro, CJA, Pereira, MM, Kozhevnikova, EF, Kozhevnikov, IV ORCID: 0000-0003-2453-5256, Gusevskaya, EV and da Silva Rocha, KA
(2020)
Heteropoly acid catalysts in upgrading of biorenewables: Synthesis of para-menthenic fragrance compounds from α-pinene oxide.
Catalysis Today, 344.
pp. 166-170.
Text
Gusevskaya manuscript revised .doc - Author Accepted Manuscript Download (426kB) |
Abstract
© 2018 Elsevier B.V. The isomerization of α-pinene oxide in the presence of Cs2.5H0.5PW12O40 (CsPW) heteropolysalt as solid acid catalyst is reported. The reactions were performed in various solvents, which allowed to obtain trans-carveol, trans-sobrerol and pinol in 60–80% yield each, which exceed the yields reported so far. The CsPW catalyst could be recovered and reused without loss of its activity and selectivity.
Item Type: | Article |
---|---|
Uncontrolled Keywords: | Biomass-based feedstock, Isomerization, Heterogeneous catalysis, Heteropoly compounds, alpha-pinene oxide |
Depositing User: | Symplectic Admin |
Date Deposited: | 07 Jan 2019 11:07 |
Last Modified: | 19 Jan 2023 01:08 |
DOI: | 10.1016/j.cattod.2018.12.023 |
Related URLs: | |
URI: | https://livrepository.liverpool.ac.uk/id/eprint/3030844 |