Forensic Discrimination Potential of Blue, Black, Green, and Red Colored Fountain Pen Inks Commercially Used in Pakistan, by UV/Visible Spectroscopy, Thin Layer Chromatography, and Fourier Transform Infrared Spectroscopy



Sharif, Mehwish, Batool, Madeeha, Chand, Sohail, Farooqi, Zahoor Hussain ORCID: 0000-0003-3200-2935, Tirmazi, Syed Azhar Ali Shah and Athar, Makshoof
(2019) Forensic Discrimination Potential of Blue, Black, Green, and Red Colored Fountain Pen Inks Commercially Used in Pakistan, by UV/Visible Spectroscopy, Thin Layer Chromatography, and Fourier Transform Infrared Spectroscopy. INTERNATIONAL JOURNAL OF ANALYTICAL CHEMISTRY, 2019. 5980967-.

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Abstract

Examination and comparison of fountain pen inks are very important in forensic questioned documents examination in developing countries where the chances of fraud are greater in cases of cheques, marriage papers, entry of birth and death, etc. In this study, fountain pen inks of blue, black, green, and red colours that are commercially used in Pakistan have been discriminated by UV-Vis spectroscopy, TLC, and FTIR spectroscopy. We have calculated and compared the results in terms of discriminating power. UV/Visible Spectroscopy of fountain pen inks of different brands showed different composition despite their similar colours. TLC was effectively used to differentiate between the colored components of inks. FTIR results showed that each brand could be distinguished by studying the pattern of their absorption spectra that appeared due to the presence of different functional groups. On the basis of combined results of UV-VIS, TLC, and FTIR, the DP was found from 0.73-0.8 for blue, 0.80-1.0 for black, 0.5-1.0 for green, and 1.0 for red colored fountain pen inks. Overall, this study demonstrated the elevated worth of analysis of fountain pen inks commercially used in Pakistan as the study for fountain pen inks, while not very common, remains an interesting target study.

Item Type: Article
Depositing User: Symplectic Admin
Date Deposited: 07 May 2019 09:06
Last Modified: 19 Jan 2023 00:50
DOI: 10.1155/2019/5980967
Open Access URL: http://doi.org/10.1155/2019/5980967
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URI: https://livrepository.liverpool.ac.uk/id/eprint/3040010