Nguyen Tien, Cong 
ORCID: 0000-0003-1427-0653, Le Thi Thu, Huong, Nguyen Van, Thin, Vu Quoc, Trung, Vu Quoc, Manh, Pham Chien, Thang and Van Meervelt, Luc ORCID: 0000-0003-2186-5209
(2018)
Crystal structure of (<i>E</i>)<i>-N</i>'-[1-(4-amino-phen-yl)ethyl-idene]-2-hy-droxy-5-iodo-benzohydrazide methanol monosolvate.
Acta crystallographica. Section E, Crystallographic communications, 74 (Pt 7).
pp. 910-914.
|
Text
Crystal structure of (E)-N'-[1-(4-amino-phen-yl)ethyl-idene]-2-hy-droxy-5-iodo-benzohydrazide methanol monosolvate.pdf - Published version Download (1MB) | Preview |
Abstract
In the title compound, C<sub>15</sub>H<sub>14</sub>IN<sub>3</sub>O<sub>2</sub>·CH<sub>3</sub>OH, two aromatic rings are linked by an <i>N</i>-substituted hydrazide function. The dihedral angle between the aromatic rings is 10.53 (8)°. The stereochemistry about the imine function is <i>E</i>. The methanol mol-ecule forms an O-H⋯O hydrogen bond to the hydrazide O atom. In the crystal, chains of mol-ecules running along the <i>c</i>-axis direction are formed by O-H⋯O hydrogen bonds. Adjacent chains are linked through N-H⋯O hydrogen bonds and π-π stacking inter-actions. The inter-molecular inter-actions in the crystal packing were investigated using Hirshfeld surface analysis, which indicated that the most significant contacts are H⋯H (38.2%), followed by C⋯H/H⋯C (20.6%), O⋯H/H⋯O (11.1%) and I⋯H/H⋯I (9.7%).
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | Hirshfeld surface, N-substituted hydrazide, crystal structure, salicylic acid |
| Depositing User: | Symplectic Admin |
| Date Deposited: | 29 May 2019 15:38 |
| Last Modified: | 19 Jan 2023 00:42 |
| DOI: | 10.1107/s2056989018008204 |
| Related URLs: | |
| URI: | https://livrepository.liverpool.ac.uk/id/eprint/3043319 |
Dimensions
Dimensions
