Green synthesis and crystal structure of 3-(benzo-thia-zol-2-yl)thio-phene.

Nguyen Ngoc, Linh, Vu Quoc, Trung, Duong Quoc, Hoan, Vu Quoc, Manh, Truong Minh, Luong, Thang Pham, Chien and Van Meervelt, Luc ORCID: 0000-0003-2186-5209 (2017) Green synthesis and crystal structure of 3-(benzo-thia-zol-2-yl)thio-phene. Acta crystallographica. Section E, Crystallographic communications, 73 (Pt 11). pp. 1647-1651.

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Abstract

The title compound, C₁₁H₇NS₂, was prepared in high yield (87%) using a solvent-free microwave-assisted synthesis. The structure shows whole-mol-ecule disorder with occupancies for two orientations (A and B) of 0.4884 (10) and 0.5116 (10), respectively. The thio-phene and benzo-thia-zole rings are almost planar and make dihedral angles of 10.02 (18) and 12.54 (19)° for orientations A and B, respectively. Slipped π-π stacking between the aromatic rings, together with C-H⋯π, C-H⋯S and C-H⋯N inter-actions, result in a herringbone motif in the crystal packing.

Item Type:	Article
Uncontrolled Keywords:	benzo­thia­zole, crystal structure, microwave-assisted synthesis, solvent-free, thio­phene, whole-mol­ecule disorder
Depositing User:	Symplectic Admin
Date Deposited:	30 May 2019 09:43
Last Modified:	19 Jan 2023 00:42
DOI:	10.1107/s2056989017014530
Related URLs:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3043322