Kinzhalov, Mikhail A and Luzyanin, Konstantin V ORCID: 0000-0001-9312-7139
(2019)
Reactivity of acyclic diaminocarbene ligands.
COORDINATION CHEMISTRY REVIEWS, 399.
p. 213014.
Text
2.Rev_ADC31.docx - Author Accepted Manuscript Download (1MB) |
Abstract
Acyclic diaminocarbenes (ADCs) are powerful ligands with a broad application scope in organometallic chemistry, catalysis, photophysics and crystal engineering. Although the preparation and application of metal-ADC species are discussed in many reports, the reactivity of ADC ligands is much less scrutinised. However, studies emerged indicate that ADC ligands, in particular, those prepared via the metal-mediated nucleophilic addition to isocyanides, can be further converted into various post-functionalised derivatives. In this review, we attempt for the first time to rationalise the most important reactivity modes of metal-ADC species reported up to date.
Item Type: | Article |
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Uncontrolled Keywords: | Acyclic diaminocarbene, Carbene ligands, Reactivity modes, Metal complexes, Deprotonation |
Depositing User: | Symplectic Admin |
Date Deposited: | 09 Oct 2019 12:36 |
Last Modified: | 19 Jan 2023 00:23 |
DOI: | 10.1016/j.ccr.2019.213014 |
Related URLs: | |
URI: | https://livrepository.liverpool.ac.uk/id/eprint/3057584 |