There is nothing wrong with being soft: using sulfur ligands to increase axiality in a Dy(iii) single-ion magnet.

Canaj, Angelos B ORCID: 0000-0002-4944-7909, Dey, Sourav, Céspedes, Oscar, Wilson, Claire, Rajaraman, Gopalan and Murrie, Mark (2020) There is nothing wrong with being soft: using sulfur ligands to increase axiality in a Dy(iii) single-ion magnet. Chemical communications (Cambridge, England), 56 (10). pp. 1533-1536.

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Official URL: http://dx.doi.org/10.1039/c9cc07292f

Abstract

A new air-stable sulfur-ligated Dy(iii) single-ion magnet has been successfully isolated with Ueff = 638 K and hysteresis loops open up to 7 K. In silico studies show that the S co-ligands significantly boost the axiality and that Te- and Se-donors have the potential to further enhance the magnetic properties.

Item Type:	Article
Depositing User:	Symplectic Admin
Date Deposited:	31 Jan 2020 11:16
Last Modified:	19 Jan 2023 00:05
DOI:	10.1039/c9cc07292f
Open Access URL:	https://doi.org/10.1039/C9CC07292F
Related URLs:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3072825