Alkaline Water Oxidation Using a Bimetallic Phospho-Boride Electrocatalyst

Chunduri, Avani, Gupta, Suraj ORCID: 0000-0001-8128-5869, Patel, Maulik ORCID: 0000-0002-3214-5752, Forster, Mark, Cowan, Alexander J ORCID: 0000-0001-9032-3548 and Patel, Nainesh (2020) Alkaline Water Oxidation Using a Bimetallic Phospho-Boride Electrocatalyst. CHEMSUSCHEM, 13 (24). pp. 6534-6540.

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Abstract

New oxygen evolution reaction (OER) electrocatalysts based on low-cost elements, which set new benchmark levels of activity, are vital if water electrolysis is to be applied on a global scale. Herein, a low-cost bimetallic phospho-boride catalyst was developed that showed outstanding OER activity of approximately 195 mV to achieve 10 mA cm^-2 in alkaline water electrolysis, with a minimal catalyst loading of 0.3 mg cm^-2 . The contrasting electron transfer property of the metal borides and phosphides when combined in phospho-boride modulated the electron density of the Co atom, yielding highly active CoOOH species at lower potentials. The addition of Mo at low levels further enhanced the activity by increasing the surface area and by formation of nano-crystalline domains. The combined contributions from each of the components resulted in a new benchmark mass activity of 666 A g^-1 at 300 mV overpotential. This work presents a new avenue towards fabricating electrode materials with exceptional performances.

Item Type:	Article
Uncontrolled Keywords:	alkaline water oxidation, low-cost electrocatalysts, mass activity, metal phospho-borides, oxygen evolution reaction
Depositing User:	Symplectic Admin
Date Deposited:	28 Oct 2020 14:24
Last Modified:	18 Jan 2023 23:25
DOI:	10.1002/cssc.202002269
Related URLs:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3105404