Recent Development in the Synthesis and Catalytic Application of Iridacycles.

Chen, Zhenyu ORCID: 0000-0001-7714-9936, Kacmaz, Aysecik ORCID: 0000-0001-8420-6855 and Xiao, Jianliang ORCID: 0000-0003-2010-247X (2021) Recent Development in the Synthesis and Catalytic Application of Iridacycles. Chemical record (New York, N.Y.), 21 (6). pp. 1506-1534.

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Official URL: http://dx.doi.org/10.1002/tcr.202100051

Abstract

Cyclometallated complexes are well-known and have found many applications. This article provides a short review on the progress made in the synthesis and application to catalysis of cyclometallated half-sandwich Cp*Ir(III) complexes (Cp*: pentamethylcyclopentadienyl) since 2017. Covered in the review are iridacycles featuring conventional C,N chelates and less common metallocene and carbene-derived C,N and C,C ligands. This is followed by an overview of the studies of their applications in catalysis ranging from asymmetric hydrogenation, transfer hydrogenation, hydrosilylation to dehydrogenation.

Item Type:	Article
Uncontrolled Keywords:	cyclometallated complexes, dehydrogenation, hydrogenation, hydrosilylation, iridacycles, transfer hydrogenation
Divisions:	Faculty of Science and Engineering > School of Physical Sciences
Depositing User:	Symplectic Admin
Date Deposited:	07 May 2021 15:27
Last Modified:	08 Sep 2023 01:16
DOI:	10.1002/tcr.202100051
Open Access URL:	https://onlinelibrary.wiley.com/doi/10.1002/tcr.20...
Related URLs:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3121855