Creating porosity in a trianglimine macrocycle by heterochiral pairing

He, Donglin ORCID: 0000-0002-5512-8162, Clowes, Rob, Little, Marc A, Liu, Ming ORCID: 0000-0003-0008-1480 and Cooper, Andrew I ORCID: 0000-0003-0201-1021 (2021) Creating porosity in a trianglimine macrocycle by heterochiral pairing. CHEMICAL COMMUNICATIONS, 57 (50). pp. 6141-6144.

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Official URL: http://dx.doi.org/10.1039/d1cc01650d

Abstract

Macrocycles are usually non-porous or barely porous in the solid-state because of their small intrinsic cavity sizes and tendency to close-pack. Here, we use a heterochiral pairing strategy to introduce porosity in a trianglimine macrocycle, by co-crystallising two macrocycles with opposing chiralities. The stable racemic trianglimine crystal contains an interconnected pore network that has a Brunauer-Emmett-Teller (BET) surface area of 355 m2 g-1.

Item Type:	Article
Divisions:	Faculty of Science and Engineering > School of Physical Sciences
Depositing User:	Symplectic Admin
Date Deposited:	02 Jun 2021 14:50
Last Modified:	18 Jan 2023 22:36
DOI:	10.1039/d1cc01650d
Related URLs:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3124902