Quantification of branching within high molecular weight polymers with polyester backbones formed by transfer-dominated branching radical telomerisation (TBRT)

Cassin, Savannah R, Flynn, Sean ORCID: 0000-0001-6028-3389, Chambon, Pierre and Rannard, Steve P ORCID: 0000-0002-6946-1097 (2021) Quantification of branching within high molecular weight polymers with polyester backbones formed by transfer-dominated branching radical telomerisation (TBRT). RSC ADVANCES, 11 (39). pp. 24374-24380.

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Official URL: http://dx.doi.org/10.1039/d1ra03886a

Abstract

New branched polymerisations offer previously inaccessible macromolecules and architectural understanding is important as it provides insight into the branching mechanism and enables the determination of structure-property relationships. Here we present a detailed inverse gated <sup>13</sup>C NMR characterisation of materials derived from the very recently reported Transfer-dominated Branching Radical Telomerisation (TBRT) approach to quantify branching and provide an insight into cyclisation.

Item Type:	Article
Divisions:	Faculty of Science and Engineering > School of Physical Sciences
Depositing User:	Symplectic Admin
Date Deposited:	09 Aug 2021 10:46
Last Modified:	18 Jan 2023 21:33
DOI:	10.1039/d1ra03886a
Open Access URL:	https://pubs.rsc.org/en/content/articlehtml/2021/r...
Related URLs:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3132902