Impact of multi-vinyl taxogen dimensions on high molecular weight soluble polymer synthesis using transfer-dominated branching radical telomerisation



Penrhyn-Lowe, Oliver B, Flynn, Sean ORCID: 0000-0001-6028-3389, Cassin, Savannah R, Mckeating, Samuel, Lomas, Sarah, Wright, Stephen, Chambon, Pierre and Rannard, Steve P ORCID: 0000-0002-6946-1097
(2021) Impact of multi-vinyl taxogen dimensions on high molecular weight soluble polymer synthesis using transfer-dominated branching radical telomerisation. POLYMER CHEMISTRY, 12 (44). pp. 6472-6483.

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Abstract

<jats:p>The creation of branched polymers by TBRT is influenced by the molecular dimensions of the polymerising species. A mechanistic understanding is presented that includes a radical lifetime sphere model that is unique to telomerisation conditions used.</jats:p>

Item Type: Article
Divisions: Faculty of Science and Engineering > School of Physical Sciences
Depositing User: Symplectic Admin
Date Deposited: 08 Dec 2021 15:26
Last Modified: 18 Jan 2023 21:24
DOI: 10.1039/d1py01103k
Open Access URL: https://pubs.rsc.org/en/content/articlelanding/202...
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URI: https://livrepository.liverpool.ac.uk/id/eprint/3143829