Carbon Nanofiber/SiO<sub>2</sub> Nanoparticle/HDPE Composites as Physically Resilient and Submersible Water-Repellent Coatings on HDPE Substrates



Upton, Rebekah L, Fedosyuk, Aleksandra, Edel, Joshua B and Crick, Colin R ORCID: 0000-0001-9674-3973
(2021) Carbon Nanofiber/SiO<sub>2</sub> Nanoparticle/HDPE Composites as Physically Resilient and Submersible Water-Repellent Coatings on HDPE Substrates. ACS APPLIED NANO MATERIALS, 4 (10). pp. 10090-10102.

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Abstract

Here, we introduce high-strength carbon nanofibers (CNFs) into optimized polymer-nanoparticle composite formulations [modified SiO2 nanoparticles/high-density polyethylene (HDPE)] to generate superhydrophobic surface coatings that are directly integrated into HDPE substrates. This is achieved through the use of a parallel plate hot pressing process and a unique design approach that considers the chemical properties of individual formulation components within a ternary system. Subsequently, this enables the generation of resilient, high-functioning, nano/microscale materials while increasing potential lifetimes, through integrating self-cleaning functionality into the polymer. The most encouraging nanocomposite surface coating was found to surpass 100 abrasion cycles while retaining its high water repellency, displaying a static contact angle of 150 ± 3° and tilting angle of 18 ± 7° after 4 weeks of continual submersion (from values of 156 ± 3 and 5 ± 1°, respectively), under a hydrostatic pressure of 7.85 kPa (80 cm depth), where it was found to remain fully functional as a self-cleaning coating.

Item Type: Article
Uncontrolled Keywords: superhydrophobic, self-cleaning, resilient, plastron, composite
Divisions: Faculty of Science and Engineering > School of Physical Sciences
Depositing User: Symplectic Admin
Date Deposited: 03 Dec 2021 16:42
Last Modified: 19 Oct 2023 09:26
DOI: 10.1021/acsanm.1c01498
Open Access URL: https://pubs.acs.org/doi/10.1021/acsanm.1c01498
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URI: https://livrepository.liverpool.ac.uk/id/eprint/3144537