Glass Formation in Hybrid Organic-Inorganic Perovskites

Ye, Chumei, McHugh, Lauren N ORCID: 0000-0003-2032-0450, Chen, Celia, Dutton, Sian E and Bennett, Thomas D (2023) Glass Formation in Hybrid Organic-Inorganic Perovskites. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 62 (28). e202302406-.

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Abstract

Crystalline materials have governed the development of hybrid organic-inorganic perovskites (HOIPs), giving rise to a variety of fascinating applications such as solar cells and optoelectronic devices. With increasing interest in non-crystalline systems, the glassy state of HOIPs has recently been identified. Here, the basic building blocks of crystalline HOIPs appear to be retained, though their glasses lack long-range periodic order. The emerging family of glasses formed from HOIPs exhibits diverse properties, complementary to their crystalline state. This mini review describes the chemical diversity of both three-dimensional and two-dimensional crystalline HOIPs and demonstrates how glasses are produced from these materials. Specifically, current achievements in melt-quenched glasses formed from HOIPs are highlighted. We conclude with our perspective on the future of this new family of materials.

Item Type:	Article
Uncontrolled Keywords:	Amorphization, Glass, Hybrid Organic-Inorganic Perovskite, Thermal Analysis, Vitrification
Divisions:	Faculty of Science and Engineering > School of Physical Sciences
Depositing User:	Symplectic Admin
Date Deposited:	29 Sep 2023 15:34
Last Modified:	29 Sep 2023 15:35
DOI:	10.1002/anie.202302406
Open Access URL:	https://doi.org/10.1002/anie.202302406
Related URLs:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3173237