Amorphous quaternary alloy nanoplates for efficient catalysis of hydrogen evolution reaction



Bai, Qianyun, Yan, Xiaoxiao, Liu, Da, Xiang, Kang, Tu, Xin ORCID: 0000-0002-6376-0897, Guo, Yanhui and Wu, Renbing
(2024) Amorphous quaternary alloy nanoplates for efficient catalysis of hydrogen evolution reaction. Journal of Alloys and Compounds, 972. p. 172730.

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Abstract

Developing a highly efficient non-precious transition metal-based electrocatalyst via a facile approach toward the hydrogen evolution reaction (HER) is critical for large-scale hydrogen production but still remains challenging. Herein, a cost-effective electrochemical deposition strategy is rationally proposed to construct amorphous quaternary FeCoNiCu alloy nanosheets supported on nickel foam (NF) towards this challenge. Benefiting from the synergistic effect of multi-metal atoms interaction and the high exposure of active sites caused by abundant open voids, the as-synthesized FeCoNiCu/NF electrode exhibits high catalytic activity and robustness toward HER in alkaline solution, requiring an overpotential of only 35 mV to reach a current density of 10 mA cm–2. This study may pave a new avenue to design advanced electrocatalyst for energy conversion.

Item Type: Article
Uncontrolled Keywords: 7 Affordable and Clean Energy
Divisions: Faculty of Science and Engineering > School of Electrical Engineering, Electronics and Computer Science
Depositing User: Symplectic Admin
Date Deposited: 11 Dec 2023 11:53
Last Modified: 17 Mar 2024 19:01
DOI: 10.1016/j.jallcom.2023.172730
Related URLs:
URI: https://livrepository.liverpool.ac.uk/id/eprint/3177256