Phosphorescent Cyclometalated Palladium(II) and Platinum(II) Complexes Derived from Diaminocarbene Precursors.

Kashina, Maria V ORCID: 0000-0002-3063-3074, Luzyanin, Konstantin V ORCID: 0000-0001-9312-7139, Dar'in, Dmitry V ORCID: 0000-0002-0413-7413, Bezzubov, Stanislav I and Kinzhalov, Mikhail A ORCID: 0000-0001-5055-1212 (2024) Phosphorescent Cyclometalated Palladium(II) and Platinum(II) Complexes Derived from Diaminocarbene Precursors. Inorganic chemistry, 63 (12). pp. 5315-5319.

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Abstract

Metal-mediated self-assembly of isocyanides and methyl 4-aminopyrimidine-5-carboxylate leads to luminescent Pd^II and Pt^II complexes featuring C,N-cyclometalated acyclic diaminocarbene (ADC) ligands. The solid-state luminescent properties of these diaminocarbene derivatives are attributed to their triplet-state metal/metal-to-ligand charge-transfer (³MMLCT) nature, which is driven by attractive intermolecular M···M interactions further reinforced by the intramolecular π-π interactions even in the structure of the Pd compound, which is the first Pd-ADC phosphor reported.

Item Type:	Article
Divisions:	Faculty of Science and Engineering > School of Physical Sciences
Depositing User:	Symplectic Admin
Date Deposited:	02 Apr 2024 16:24
Last Modified:	02 Apr 2024 16:24
DOI:	10.1021/acs.inorgchem.3c03346
Related URLs:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3180010