Luzyanin, Konstantin V ORCID: 0000-0001-9312-7139, Marianov, Aleksei N, Kislitsyn, Pavel G and Ananikov, Valentine P
(2017)
Substrate-Selective C-H Functionalization for the Preparation of Organosulfur Compounds from Crude Oil-Derived Components.
ACS OMEGA, 2 (4).
pp. 1419-1423.
Text
056_ACSO.pdf - Published version Download (1MB) |
Abstract
The direct utilization of a natural feedstock in organic synthesis is an utmost challenge because the selective production of one product from a mixture of starting materials requires unprecedented substrate selectivity. In the present study, a simple and convenient procedure is evaluated for the substrate-selective alkenylation of a single component in a mixture of organosulfur compounds. Pd-catalyzed alkenylation of two-, three-, four-, and five-component mixtures of crude oil-derived sulfur species led to the exclusive C-H functionalization of only one compound. The observed remarkable substrate selectivity opens new opportunities for sustainable organic synthesis.
Item Type: | Article |
---|---|
Depositing User: | Symplectic Admin |
Date Deposited: | 12 Jun 2017 06:54 |
Last Modified: | 19 Jan 2023 07:03 |
DOI: | 10.1021/acsomega.7b00137 |
Related URLs: | |
URI: | https://livrepository.liverpool.ac.uk/id/eprint/3007901 |