Directing the mechanism of CO<sub>2</sub> reduction by a Mn catalyst through surface immobilization



Walsh, James J, Forster, Mark ORCID: 0000-0002-8077-7690, Smith, Charlotte L, Neri, Gaia ORCID: 0000-0003-1326-9327, Potter, Richard J ORCID: 0000-0003-0896-4536 and Cowan, Alexander J ORCID: 0000-0001-9032-3548
(2018) Directing the mechanism of CO<sub>2</sub> reduction by a Mn catalyst through surface immobilization. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 20 (10). pp. 6811-6816.

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Abstract

Immobilization of a Mn polypyridyl CO<sub>2</sub> reduction electrocatalyst on nanocrystalline TiO<sub>2</sub> electrodes yields an active heterogeneous system and also significantly triggers a change in voltammetric and catalytic behaviour, relative to in solution. A combination of spectroelectrochemical techniques are presented here to elucidate the mechanism of the immobilized catalyst in situ.

Item Type: Article
Depositing User: Symplectic Admin
Date Deposited: 22 Feb 2018 15:23
Last Modified: 06 Feb 2024 23:22
DOI: 10.1039/c7cp08537k
Related URLs:
URI: https://livrepository.liverpool.ac.uk/id/eprint/3018332