Neri, Gaia 
ORCID: 0000-0003-1326-9327, Walsh, James J, Wilson, Calum, Reynal, Anna, Lim, Jason YC, Li, Xiaoe, White, Andrew JP, Long, Nicholas J, Durrant, James R and Cowan, Alexander J ORCID: 0000-0001-9032-3548
(2015)
A functionalised nickel cyclam catalyst for CO2 reduction: electrocatalysis, semiconductor surface immobilisation and light-driven electron transfer.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 17 (3).
pp. 1562-1566.
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Abstract
The immobilisation of electrocatalysts for CO2 reduction onto light harvesting semiconductors is proposed to be an important step towards developing more efficient CO2 reduction photoelectrodes. Here, we report a low cost nickel cyclam complex covalently anchored to a metal oxide surface. Using transient spectroscopy we validate the role of surface immobilisation on enhancing the rate of photoelectron transfer. Furthermore [Ni(1,4,8,11-tetraazacyclotetradecane-6-carboxylic acid)](2+) (2) is shown to be a very active electrocatalyst in solution.
| Item Type: | Article |
|---|---|
| Subjects: | ?? QD ?? |
| Depositing User: | Symplectic Admin |
| Date Deposited: | 24 Mar 2015 15:08 |
| Last Modified: | 16 Dec 2022 16:55 |
| DOI: | 10.1039/c4cp04871g |
| Related URLs: | |
| URI: | https://livrepository.liverpool.ac.uk/id/eprint/2008884 |
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