Villa-Marcos, Barbara, Tang, Weijun, Wu, Xiaofeng ORCID: 0000-0001-5549-8836 and Xiao, Jianliang ORCID: 0000-0003-2010-247X
(2013)
A highly active cyclometallated iridium catalyst for the hydrogenation of imines.
ORGANIC & BIOMOLECULAR CHEMISTRY, 11 (40).
pp. 6934-6939.
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Abstract
A cyclometallated iridium complex containing an imino ligand has been shown to catalyse the hydrogenation of imines. The catalyst is highly active and selective for imino bonds, with a wide variety of imines being hydrogenated in less than 1 hour at a substrate/catalyst (S/C) ratio of 2000 at 20 bar H2 pressure and 75 °C.
Item Type: | Article |
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Uncontrolled Keywords: | Iridium, Amines, Imines, Organometallic Compounds, Molecular Structure, Hydrogenation, Catalysis |
Depositing User: | Symplectic Admin |
Date Deposited: | 08 Apr 2016 15:41 |
Last Modified: | 16 Dec 2022 02:44 |
DOI: | 10.1039/c3ob41150h |
Related URLs: | |
URI: | https://livrepository.liverpool.ac.uk/id/eprint/3000100 |