Dynamic flow synthesis of porous organic cages



Briggs, Michael E, Slater, Anna G ORCID: 0000-0002-1435-4331, Lunt, Neil, Jiang, Shan, Little, Marc A, Greenaway, Rebecca L, Hasell, Tom ORCID: 0000-0003-4736-0604, Battilocchio, Claudio, Ley, Steven V and Cooper, Andrew I ORCID: 0000-0003-0201-1021
(2015) Dynamic flow synthesis of porous organic cages CHEMICAL COMMUNICATIONS, 51 (98). pp. 17390-17393. ISSN 1359-7345, 1364-548X

[thumbnail of Flow manuscript final.pdf] Text
Flow manuscript final.pdf - Unspecified

Download (529kB)
[thumbnail of Cages in Flow ESI_Final.pdf] Text
Cages in Flow ESI_Final.pdf - Unspecified

Download (2MB)

Abstract

The dynamic covalent synthesis of two imine-based porous organic cages was successfully transferred from batch to continuous flow. The same flow reactor was then used to scramble the constituents of these two cages in differing ratios to form cage mixtures. Preparative HPLC purification of one of these mixtures allowed rapid access to a desymmetrised cage molecule.

Item Type: Article
Uncontrolled Keywords: 3403 Macromolecular and Materials Chemistry, 40 Engineering, 3405 Organic Chemistry, 34 Chemical Sciences
Depositing User: Symplectic Admin
Date Deposited: 28 Apr 2016 14:14
Last Modified: 16 Jun 2026 12:05
DOI: 10.1039/c5cc07447a
Related Websites:
URI: https://livrepository.liverpool.ac.uk/id/eprint/3000675
Disclaimer: The University of Liverpool is not responsible for content contained on other websites from links within repository metadata. Please contact us if you notice anything that appears incorrect or inappropriate.