Steiner, A 
ORCID: 0000-0002-4315-6123, Jones, AC, Hanke, F and Song, S
(2016)
The solid state structures of the high and low temperature phases of dimethylcadmium
Chemical Communications (London), 52 (66).
pp. 10144-10146.
ISSN 0009-241X, 1364-548X
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Abstract
The solid state structure of dimethylcadmium, a classic organometallic compound with a long history, has remained elusive for almost a century. X-ray crystallography and density functional theory reveal similar phase behaviour as in dimethylzinc. The high temperature tetragonal phase, α-Me<inf>2</inf>Cd, exhibits two-dimensional disorder, while the low temperature monoclinic phase, β-Me<inf>2</inf>Cd, is ordered. Both phases contain linearly coordinated cadmium atoms. While the methyl groups are staggered in the α-phase, they are eclipsed in the β-phase.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | 3402 Inorganic Chemistry, 34 Chemical Sciences |
| Depositing User: | Symplectic Admin |
| Date Deposited: | 22 Jul 2016 15:35 |
| Last Modified: | 01 Mar 2026 11:41 |
| DOI: | 10.1039/C6CC05851E |
| Related Websites: | |
| URI: | https://livrepository.liverpool.ac.uk/id/eprint/3002484 |
| Disclaimer: | The University of Liverpool is not responsible for content contained on other websites from links within repository metadata. Please contact us if you notice anything that appears incorrect or inappropriate. |
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