Structural and magnetic characterization of the complete delafossite solid solution (CuAlO2){1-x}(CuCrO2){x}

Barton, Phillip T, Seshadri, Ram, Knöller, Andrea and Rosseinsky, Matthew J ORCID: 0000-0002-1910-2483
(2011) Structural and magnetic characterization of the complete delafossite solid solution (CuAlO2){1-x}(CuCrO2){x}. J. Phys.: Condens. Matter, 24. 016002 - ?.

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We have prepared the complete delafossite solid solution series between diamagnetic CuAlO2 and the t2g^3 frustrated antiferromagnet CuCrO2. The evolution with composition x in CuAl(1-x)Cr(x)O2 of the crystal structure and magnetic properties has been studied and is reported here. The room-temperature unit cell parameters follow the Vegard law and increase with x as expected. The effective moment is equal to the Cr^3+ spin-only S = 3/2 value throughout the entire solid solution. Theta is negative, indicating that the dominant interactions are antiferromagnetic, and its magnitude increases with Cr substitution. For dilute Cr compositions, J_BB was estimated by mean-field theory to be 2.0 meV. Despite the sizable Theta, long-range antiferromagnetic order does not develop until very large x, and is preceeded by glassy behavior. Data presented here, and that on dilute Al-substitution from Okuda et al., suggest that the reduction in magnetic frustration due to the presence of non-magnetic Al does not have as dominant an effect on magnetism as chemical disorder and dilution of the magnetic exchange. For all samples, the 5 K isothermal magnetization does not saturate in fields up to 5 T and minimal hysteresis is observed. The presence of antiferromagnetic interactions is clearly evident in the sub-Brillouin behavior with a reduced magnetization per Cr atom. An inspection of the scaled Curie plot reveals that significant short-range antiferromagnetic interactions occur in CuCrO2 above its Neel temperature, consistent with its magnetic frustration. Uncompensated short-range interactions are present in the Al-substituted samples and are likely a result of chemical disorder.

Item Type: Article
Uncontrolled Keywords: cond-mat.mtrl-sci, cond-mat.mtrl-sci
Depositing User: Symplectic Admin
Date Deposited: 28 Jul 2016 14:40
Last Modified: 28 Apr 2022 03:15
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