The hydride anion in an extended transition metal oxide array:: LaSrCoO₃H_0.7

Hayward, MA, Cussen, EJ, Claridge, JB ORCID: 0000-0003-4849-6714, Bieringer, M, Rosseinsky, MJ ORCID: 0000-0002-1910-2483, Kiely, CJ, Blundell, SJ, Marshall, IM and Pratt, FL (2002) The hydride anion in an extended transition metal oxide array:: LaSrCoO₃H_0.7 SCIENCE, 295 (5561). pp. 1882-1884. ISSN 0036-8075, 1095-9203

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Abstract

We present the synthesis and structural characterization of a transition metal oxide hydride, LaSrCoO<inf>3</inf>H<inf>0.7</inf>, which adopts an unprecedented structure in which oxide chains are bridged by hydride anions to form a two-dimensional extended network. The metal centers are strongly coupled by their bonding with both oxide and hydride ligands to produce magnetic ordering at temperatures up to at least 350 kelvin. The synthetic route is sufficiently general to allow the prediction of a new class of transition metal-containing electronic and magnetic materials.

Item Type:	Article
Additional Information:	6 pages, including 3 figures
Uncontrolled Keywords:	cond-mat.str-el, cond-mat.str-el, cond-mat.mtrl-sci
Depositing User:	Symplectic Admin
Date Deposited:	01 Aug 2016 10:27
Last Modified:	16 Jun 2026 05:51
DOI:	10.1126/science.1068321
Related Websites:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3002652
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