Al-Owaedi, Oday A, Milan, David C ORCID: 0000-0002-2077-7920, Oerthel, Marie-Christine, Bock, Soren, Yufit, Dmitry S, Howard, Judith AK, Higgins, Simon J ORCID: 0000-0003-3518-9061, Nichols, Richard J ORCID: 0000-0002-1446-8275, Lambert, Colin J, Bryce, Martin R et al (show 1 more authors)
(2016)
Experimental and Computational Studies of the Single-Molecule Conductance of Ru(II) and Pt(II) <i>trans</i>-Bis(acetylide) Complexes.
ORGANOMETALLICS, 35 (17).
pp. 2944-2954.
Text
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Abstract
The single-molecule conductance of metal complexes of the general forms trans-Ru(C≡CArC≡CY)2(dppe)2 and trans-Pt(C≡CArC≡CY)2(PPh3)2 (Ar = 1,4-C6H2-2,5-(OC6H13)2; Y = 4-C5H4N, 4-C6H4SMe) have been determined using the STM I(s) technique. The complexes display high conductance (Y = 4-C5H4N, M = Ru (0.4 ± 0.18 nS), Pt (0.8 ± 0.5 nS); Y = 4-C6H5SMe, M = Ru (1.4 ± 0.4 nS), Pt (1.8 ± 0.6 nS)) for molecular structures of ca. 3 nm in length, which has been attributed to transport processes arising from tunneling through the tails of LUMO states.
Item Type: | Article |
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Depositing User: | Symplectic Admin |
Date Deposited: | 31 Aug 2016 08:52 |
Last Modified: | 17 Oct 2023 03:05 |
DOI: | 10.1021/acs.organomet.6b00472 |
Related URLs: | |
URI: | https://livrepository.liverpool.ac.uk/id/eprint/3003088 |