Sprick, Reiner Sebastian, Bonillo, Baltasar, Clowes, Rob, Guiglion, Pierre, Brownbill, Nick J, Slater, Benjamin J, Blanc, Frederic 
ORCID: 0000-0001-9171-1454, Zwijnenburg, Martijn A, Adams, Dave J and Cooper, Andrew I ORCID: 0000-0003-0201-1021
(2016)
Visible‐Light‐Driven Hydrogen Evolution Using Planarized Conjugated Polymer Photocatalysts.
Angewandte Chemie International Edition, 55 (5).
pp. 1792-1796.
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Abstract
Linear poly(p‐phenylene)s are modestly active UV photocatalysts for hydrogen production in the presence of a sacrificial electron donor. Introduction of planarized fluorene, carbazole, dibenzo[b,d]thiophene or dibenzo[b,d]thiophene sulfone units greatly enhances the H2 evolution rate. The most active dibenzo[b,d]thiophene sulfone co‐polymer has a UV photocatalytic activity that rivals TiO2, but is much more active under visible light. The dibenzo[b,d]thiophene sulfone co‐polymer has an apparent quantum yield of 2.3 % at 420 nm, as compared to 0.1 % for platinized commercial pristine carbon nitride.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | conjugated polymer, extended conjugation, photocatalysis, planarization, water splitting |
| Depositing User: | Symplectic Admin |
| Date Deposited: | 09 Feb 2017 16:35 |
| Last Modified: | 19 Jan 2023 07:19 |
| DOI: | 10.1002/anie.201510542 |
| Related URLs: | |
| URI: | https://livrepository.liverpool.ac.uk/id/eprint/3005636 |
Available Versions of this Item
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Visible-Light-Driven Hydrogen Evolution Using Planarized Conjugated Polymer Photocatalysts. (deposited 19 Aug 2016 08:46)
- Visible‐Light‐Driven Hydrogen Evolution Using Planarized Conjugated Polymer Photocatalysts. (deposited 09 Feb 2017 16:35) [Currently Displayed]
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