Substrate-Selective C-H Functionalization for the Preparation of Organosulfur Compounds from Crude Oil-Derived Components

Luzyanin, Konstantin V ORCID: 0000-0001-9312-7139, Marianov, Aleksei N, Kislitsyn, Pavel G and Ananikov, Valentine P (2017) Substrate-Selective C-H Functionalization for the Preparation of Organosulfur Compounds from Crude Oil-Derived Components. ACS OMEGA, 2 (4). pp. 1419-1423.

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Official URL: http://dx.doi.org/10.1021/acsomega.7b00137

Abstract

The direct utilization of a natural feedstock in organic synthesis is an utmost challenge because the selective production of one product from a mixture of starting materials requires unprecedented substrate selectivity. In the present study, a simple and convenient procedure is evaluated for the substrate-selective alkenylation of a single component in a mixture of organosulfur compounds. Pd-catalyzed alkenylation of two-, three-, four-, and five-component mixtures of crude oil-derived sulfur species led to the exclusive C-H functionalization of only one compound. The observed remarkable substrate selectivity opens new opportunities for sustainable organic synthesis.

Item Type:	Article
Depositing User:	Symplectic Admin
Date Deposited:	12 Jun 2017 06:54
Last Modified:	19 Jan 2023 07:03
DOI:	10.1021/acsomega.7b00137
Related URLs:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3007901