Shape Selectivity by Guest- Driven Restructuring of a Porous Material


Warren, JE, Perkins, CG, Jelfs, KE, Boldrin, P, Chater, PA, Miller, GJ, Manning, TD ORCID: 0000-0002-7624-4306, Briggs, ME ORCID: 0000-0003-1474-1267, Stylianou, KC, Claridge, JB ORCID: 0000-0003-4849-6714 et al (show 1 more authors) (2014) Shape Selectivity by Guest- Driven Restructuring of a Porous Material. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 53 (18). pp. 4592-4596.

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Abstract

A flexible metal-organic framework selectively sorbs para- (pX) over meta-xylene (mX) by synergic restructuring around pX coupled with generation of unused void space upon mX loading. The nature of the structural change suggests more generally that flexible structures which are initially mismatched in terms of fit and capacity to the preferred guest are strong candidates for effective molecular separations.

Item Type: Article
Additional Information: CAPLUS AN 2014:517248(Journal)## TULIP Type: Articles/Papers (Journal) ##
Uncontrolled Keywords: host-guest systems, metal-organic frameworks, structural rearrangement, xylenes
Depositing User: Symplectic Admin
Date Deposited: 28 Nov 2017 12:56
Last Modified: 19 Jan 2023 06:49
DOI: 10.1002/anie.201307656
Related URLs:
URI: https://livrepository.liverpool.ac.uk/id/eprint/3013077
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