Imido-P(v) trianion supported enantiopure neutral tetrahedral Pd(II) cages

Rajasekar, P, Pandey, S, Paithankar, H, Chugh, J, Steiner, A ORCID: 0000-0002-4315-6123 and Boomishankar, R (2018) Imido-P(v) trianion supported enantiopure neutral tetrahedral Pd(II) cages Chemical Communications, 54 (15). pp. 1873-1876. ISSN 1359-7345, 1364-548X

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Abstract

Charge-neutral chiral hosts are attractive due to their ability to recognize a wide range of guest functionalities and support enantioselective processes. However, reports on such charge-neutral cages are very scarce in the literature. Here, we report an enantiomeric pair of tetrahedral Pd(ii) cages built from chiral tris(imido)phosphate trianions and oxalate linkers, which exhibit enantioselective separation capabilities for epichlorohydrin, β-butyrolactone, and 3-methyl- and 3-ethyl cyclopentanone.

Item Type:	Article
Uncontrolled Keywords:	3405 Organic Chemistry, 34 Chemical Sciences
Depositing User:	Symplectic Admin
Date Deposited:	25 Jan 2018 09:09
Last Modified:	01 Mar 2026 03:44
DOI:	10.1039/c8cc00207j
Related Websites:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3016819
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