Imido-P(V) trianion supported enantiopure neutral tetrahedral Pd(II) cages



Rajasekar, Prabhakaran, Pandey, Swechchha, Paithankar, Harshad, Chugh, Jeetender, Steiner, Alexander ORCID: 0000-0002-4315-6123 and Boomishankar, Ramamoorthy
(2018) Imido-P(V) trianion supported enantiopure neutral tetrahedral Pd(II) cages. CHEMICAL COMMUNICATIONS, 54 (15). pp. 1873-1876.

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Abstract

Charge-neutral chiral hosts are attractive due to their ability to recognize a wide range of guest functionalities and support enantioselective processes. However, reports on such charge-neutral cages are very scarce in the literature. Here, we report an enantiomeric pair of tetrahedral Pd(ii) cages built from chiral tris(imido)phosphate trianions and oxalate linkers, which exhibit enantioselective separation capabilities for epichlorohydrin, β-butyrolactone, and 3-methyl- and 3-ethyl cyclopentanone.

Item Type: Article
Depositing User: Symplectic Admin
Date Deposited: 25 Jan 2018 09:09
Last Modified: 19 Jan 2023 06:42
DOI: 10.1039/c8cc00207j
Related URLs:
URI: https://livrepository.liverpool.ac.uk/id/eprint/3016819