Rajasekar, Prabhakaran, Pandey, Swechchha, Paithankar, Harshad, Chugh, Jeetender, Steiner, Alexander ORCID: 0000-0002-4315-6123 and Boomishankar, Ramamoorthy
(2018)
Imido-P(V) trianion supported enantiopure neutral tetrahedral Pd(II) cages.
CHEMICAL COMMUNICATIONS, 54 (15).
pp. 1873-1876.
Text
C8CC00207J.pdf - Author Accepted Manuscript Download (1MB) |
Abstract
Charge-neutral chiral hosts are attractive due to their ability to recognize a wide range of guest functionalities and support enantioselective processes. However, reports on such charge-neutral cages are very scarce in the literature. Here, we report an enantiomeric pair of tetrahedral Pd(ii) cages built from chiral tris(imido)phosphate trianions and oxalate linkers, which exhibit enantioselective separation capabilities for epichlorohydrin, β-butyrolactone, and 3-methyl- and 3-ethyl cyclopentanone.
Item Type: | Article |
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Depositing User: | Symplectic Admin |
Date Deposited: | 25 Jan 2018 09:09 |
Last Modified: | 19 Jan 2023 06:42 |
DOI: | 10.1039/c8cc00207j |
Related URLs: | |
URI: | https://livrepository.liverpool.ac.uk/id/eprint/3016819 |