Near-Ideal Xylene Selectivity in Adaptive Molecular Pillar[n]arene Crystals



Jie, Kecheng, Liu, Ming, Zhou, Yujuan, Little, Marc, Pulido, Angeles, Chong, Sam, Stephenson, Andrew, Hughes, Ashlea, Sakakibara, Fumiyasu, Ogoshi, Tomoki
et al (show 4 more authors) (2018) Near-Ideal Xylene Selectivity in Adaptive Molecular Pillar[n]arene Crystals. Journal of the American Chemical Society, 140 (22). pp. 6921-6930.

[thumbnail of ja-2018-02621b_revised_manuscript.doc] Text
ja-2018-02621b_revised_manuscript.doc - Author Accepted Manuscript

Download (3MB)

Abstract

The energy-efficient separation of alkylaromatic compounds is a major industrial sustainability challenge. The use of selectively porous extended frameworks, such as zeolites or metal–organic frameworks, is one solution to this problem. Here, we studied a flexible molecular material, perethylated pillar[n]arene crystals (n = 5, 6), which can be used to separate C8 alkylaromatic compounds. Pillar[6]arene is shown to separate para-xylene from its structural isomers, meta-xylene and ortho-xylene, with 90% specificity in the solid state. Selectivity is an intrinsic property of the pillar[6]arene host, with the flexible pillar[6]arene cavities adapting during adsorption thus enabling preferential adsorption of para-xylene in the solid state. The flexibility of pillar[6]arene as a solid sorbent is rationalized using molecular conformer searches and crystal structure prediction (CSP) combined with comprehensive characterization by X-ray diffraction and 13C solid state NMR spectroscopy. The CSP study, which takes into account the structural variability of pillar[6]arene, breaks new ground in its own right and showcases the feasibility of applying CSP methods to understand and ultimately to predict the behaviour of soft, adaptive molecular crystals.

Item Type: Article
Uncontrolled Keywords: 3402 Inorganic Chemistry, 3403 Macromolecular and Materials Chemistry, 34 Chemical Sciences
Depositing User: Symplectic Admin
Date Deposited: 12 Jun 2018 10:48
Last Modified: 20 Jun 2024 21:17
DOI: 10.1021/jacs.8b02621
Related URLs:
URI: https://livrepository.liverpool.ac.uk/id/eprint/3021665