Core-Shell Crystals of Porous Organic Cages

Jiang, Shan, Du, Yi, Marcello, Marco ORCID: 0000-0002-2392-8640, Corcoran Jr, Edward W, Calabro, David C, Chong, Samantha Y ORCID: 0000-0002-3095-875X, Chen, Linjiang, Clowes, Rob, Hasell, Tom ORCID: 0000-0003-4736-0604 and Cooper, Andrew I ORCID: 0000-0003-0201-1021 (2018) Core-Shell Crystals of Porous Organic Cages. Angewandte Chemie International Edition, 57 (35). pp. 11228-11232.

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Abstract

The first examples of core–shell porous molecular crystals are described. The physical properties of the core–shell crystals, such as surface hydrophobicity, CO2 /CH4 selectivity, are controlled by the chemical composition of the shell. This shows that porous core–shell molecular crystals can exhibit synergistic properties that out-perform materials built from the individual, constituent molecules.

Item Type:	Article
Uncontrolled Keywords:	adsorption selectivity, core-shell crystals, porous cage crystals, surface hydrophobicity
Depositing User:	Symplectic Admin
Date Deposited:	21 Jun 2018 06:29
Last Modified:	19 Jan 2023 01:31
DOI:	10.1002/anie.201803244
Open Access URL:	https://doi.org/10.1002/anie.201803244
Related URLs:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3022835