Wang, Kaikai, Zhou, Jimei, Jiang, Yuting, Zhang, Miaomiao, Wang, Chao, Xue, Dong, Tang, Weijun, Sun, Huamin, Xiao, Jianliang ORCID: 0000-0003-2010-247X and Li, Chaoqun
(2019)
Selective Manganese-Catalyzed Oxidation of Hydrosilanes to Silanols under Neutral Reaction Conditions.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 58 (19).
pp. 6380-6384.
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Manganese-Catalyzed Highly Selective Oxidation of Hydrosilanes.pdf - Author Accepted Manuscript Download (1MB) |
Abstract
The first manganese-catalyzed oxidation of organosilanes to silanols with H<sub>2</sub> O<sub>2</sub> under neutral reaction conditions has been accomplished. A variety of organosilanes with alkyl, aryl, alknyl, and heterocyclic substituents were tolerated, as well as sterically hindered organosilanes. The oxidation appears to proceed by a concerted process involving a manganese hydroperoxide species. Featuring mild reaction conditions, fast oxidation, and no waste byproducts, the protocol allows a low-cost, eco-benign synthesis of both silanols and silanediols.
Item Type: | Article |
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Uncontrolled Keywords: | manganese, oxidation, silanes, silanols, synthetic methods |
Depositing User: | Symplectic Admin |
Date Deposited: | 21 Mar 2019 11:32 |
Last Modified: | 19 Jan 2023 00:56 |
DOI: | 10.1002/anie.201900342 |
Related URLs: | |
URI: | https://livrepository.liverpool.ac.uk/id/eprint/3034586 |