Synthesis of a Large, Shape-Flexible, Solvatomorphic Porous Organic Cage

Teng, Baiyang, Little, Marc A, Hasell, Tom ORCID: 0000-0003-4736-0604, Chong, Samantha Y ORCID: 0000-0002-3095-875X, Jelfs, Kim E, Clowes, Rob ORCID: 0009-0002-4686-2119, Briggs, Michael E and Cooper, Andrew I ORCID: 0000-0003-0201-1021 (2019) Synthesis of a Large, Shape-Flexible, Solvatomorphic Porous Organic Cage. CRYSTAL GROWTH & DESIGN, 19 (7). pp. 3647-3651. ISSN 1528-7483, 1528-7505

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Abstract

Porous organic cages have emerged over the last 10 years as a subclass of functional microporous materials. However, among all of the organic cages reported, large multicomponent organic cages with 20 components or more are still rare. Here, we present an [8 + 12] porous organic imine cage, <b>CC20</b>, which has an apparent surface area up to 1752 m² g^-1, depending on the crystallization and activation conditions. The cage is solvatomorphic and displays distinct geometrical cage structures, caused by crystal-packing effects, in its crystal structures. This indicates that larger cages can display a certain range of shape flexibility in the solid state, while remaining shape persistent and porous.

Item Type:	Article
Uncontrolled Keywords:	3402 Inorganic Chemistry, 3403 Macromolecular and Materials Chemistry, 34 Chemical Sciences
Depositing User:	Symplectic Admin
Date Deposited:	02 Apr 2019 09:43
Last Modified:	07 Dec 2024 06:49
DOI:	10.1021/acs.cgd.8b01761
Related URLs:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3035330