Teng, Baiyang, Little, Marc A, Hasell, Tom 
ORCID: 0000-0003-4736-0604, Chong, Samantha Y ORCID: 0000-0002-3095-875X, Jelfs, Kim E, Clowes, Rob, Briggs, Michael E and Cooper, Andrew I ORCID: 0000-0003-0201-1021
(2019)
Synthesis of a Large, Shape-Flexible, Solvatomorphic Porous Organic Cage.
CRYSTAL GROWTH & DESIGN, 19 (7).
pp. 3647-3651.
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Abstract
Porous organic cages have emerged over the last 10 years as a subclass of functional microporous materials. However, among all of the organic cages reported, large multicomponent organic cages with 20 components or more are still rare. Here, we present an [8 + 12] porous organic imine cage, <b>CC20</b>, which has an apparent surface area up to 1752 m<sup>2</sup> g<sup>-1</sup>, depending on the crystallization and activation conditions. The cage is solvatomorphic and displays distinct geometrical cage structures, caused by crystal-packing effects, in its crystal structures. This indicates that larger cages can display a certain range of shape flexibility in the solid state, while remaining shape persistent and porous.
| Item Type: | Article |
|---|---|
| Depositing User: | Symplectic Admin |
| Date Deposited: | 02 Apr 2019 09:43 |
| Last Modified: | 19 Jan 2023 00:55 |
| DOI: | 10.1021/acs.cgd.8b01761 |
| Related URLs: | |
| URI: | https://livrepository.liverpool.ac.uk/id/eprint/3035330 |
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