Metal-Organic Conjugated Microporous Polymer Containing a Carbon Dioxide Reduction Electrocatalyst

Smith, charlotte, Clowes, R ORCID: 0009-0002-4686-2119, Sprick, RS, Cooper, andrew ORCID: 0000-0003-0201-1021 and Cowan, AJ ORCID: 0000-0001-9032-3548 (2019) Metal-Organic Conjugated Microporous Polymer Containing a Carbon Dioxide Reduction Electrocatalyst Sustainable Energy and Fuels, 3 (11). pp. 2990-2994. ISSN 2398-4902, 2398-4902

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Abstract

A metal-organic conjugated micorporous polymer (CMP) containing a manganese carbonyl electrocatalyst for CO<inf>2</inf> reduction has been synthesised and electrochemically characterised. Incorporation in a rigid framework changes the behavior of the catalyst, preventing reductive dimerization. These initial studies demonstrate the feasibility of CMP electrodes that can provide both high local CO<inf>2</inf> concentrations and well defined electrocatalytic sites.

Item Type:	Article
Uncontrolled Keywords:	40 Engineering, 3403 Macromolecular and Materials Chemistry, 4016 Materials Engineering, 34 Chemical Sciences
Depositing User:	Symplectic Admin
Date Deposited:	09 Sep 2019 09:42
Last Modified:	16 Jun 2026 13:09
DOI:	10.1039/C9SE00450E
Related Websites:	Author Publisher
URI:	https://livrepository.liverpool.ac.uk/id/eprint/3053977
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