Coadou, E, Goodrich, P, Neale, AR 
ORCID: 0000-0001-7675-5432, Timperman, L, Hardacre, C, Jacquemin, J ORCID: 0000-0002-4178-8629 and Anouti, M
(2016)
Synthesis and Thermophysical Properties of Ether-Functionalized Sulfonium Ionic Liquids as Potential Electrolytes for Electrochemical Applications
Chemphyschem, 17 (23).
pp. 3992-4002.
ISSN 1439-4235, 1439-7641
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Synthesis and Thermophysical Properties of Ether-Functionalized Sulfonium Ionic Liquids as Potential Electrolytes for Electr.pdf - Published version Download (1MB) | Preview |
Abstract
During this work, a novel series of hydrophobic room temperature ionic liquids (ILs) based on five ether functionalized sulfonium cations bearing the bis{(trifluoromethyl)sulfonyl}imide, [NTf<inf>2</inf>]− anion were synthesized and characterized. Their physicochemical properties, such as density, viscosity and ionic conductivity, electrochemical window, along with thermal properties including phase transition behavior and decomposition temperature, have been measured. All of these ILs showed large liquid range temperature, low viscosity, and good conductivity. Additionally, by combining DFT calculations along with electrochemical characterization it appears that these novel ILs show good electrochemical stability windows, suitable for the potential application as electrolyte materials in electrochemical energy storage devices.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | electrochemistry, ether, ionic liquids, physical and transport properties, sulfonium |
| Depositing User: | Symplectic Admin |
| Date Deposited: | 09 Dec 2019 17:21 |
| Last Modified: | 01 Mar 2026 01:49 |
| DOI: | 10.1002/cphc.201600882 |
| Related Websites: | |
| URI: | https://livrepository.liverpool.ac.uk/id/eprint/3065633 |
| Disclaimer: | The University of Liverpool is not responsible for content contained on other websites from links within repository metadata. Please contact us if you notice anything that appears incorrect or inappropriate. |
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