Murphy, S, Ivol, F, Neale, AR 
ORCID: 0000-0001-7675-5432, Goodrich, P, Ghamouss, F, Hardacre, C and Jacquemin, J ORCID: 0000-0002-4178-8629
(2018)
Acyclic and Cyclic Alkyl and Ether-Functionalised Sulfonium Ionic Liquids Based on the [TFSI]− and [FSI]− Anions as Potential Electrolytes for Electrochemical Applications
Chemphyschem, 19 (23).
pp. 3226-3236.
ISSN 1439-4235, 1439-7641
Abstract
This work provides a study based on acyclic and cyclic sulfonium ionic liquids (ILs) with alkyl and ether-functionality on the cation paired with the bis{(trifluoromethyl)sulfonyl}imide, [TFSI]−, or the bis(fluorosulfonyl)imide, [FSI]−, as the counter anion. Herein, thermophysical characterisation of nine sulfonium-based ILs concerning the density, viscosity and conductivity and thermal properties including phase transition behaviour and decomposition temperature is reported. The electrochemical stability of the ILs was also measured by cyclic voltammetry at a glassy carbon macro-disk electrode. All of the ILs showed low melting point, low viscosity and good conductivity and could serve as potential electrolytes for energy storage devices.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | anions, electrochemistry, ether functionalisation, ionic liquids, sulfonium |
| Depositing User: | Symplectic Admin |
| Date Deposited: | 30 Jan 2020 13:22 |
| Last Modified: | 01 Mar 2026 01:49 |
| DOI: | 10.1002/cphc.201800804 |
| Open Access URL: | https://www.research.manchester.ac.uk/portal/en/pu... |
| Related Websites: | |
| URI: | https://livrepository.liverpool.ac.uk/id/eprint/3072693 |
| Disclaimer: | The University of Liverpool is not responsible for content contained on other websites from links within repository metadata. Please contact us if you notice anything that appears incorrect or inappropriate. |
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