Hemilabile Ligands as Mechanosensitive Electrode Contacts for Molecular Electronics



Ferri, Nicolò, Algethami, Norah, Vezzoli, Andrea ORCID: 0000-0002-8059-0113, Sangtarash, Sara ORCID: 0000-0003-1152-5673, McLaughlin, Maeve, Sadeghi, Hatef ORCID: 0000-0001-5398-8620, Lambert, Colin J ORCID: 0000-0003-2332-9610, Nichols, Richard J ORCID: 0000-0002-1446-8275 and Higgins, Simon J ORCID: 0000-0003-3518-9061
(2019) Hemilabile Ligands as Mechanosensitive Electrode Contacts for Molecular Electronics. Angewandte Chemie, 131 (46). pp. 16736-16742.

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Abstract

<jats:title>Abstract</jats:title><jats:p>Single‐molecule junctions that are sensitive to compression or elongation are an emerging class of nanoelectromechanical systems (NEMS). Although the molecule–electrode interface can be engineered to impart such functionality, most studies to date rely on poorly defined interactions. We focused on this issue by synthesizing molecular wires designed to have chemically defined hemilabile contacts based on (methylthio)thiophene moieties. We measured their conductance as a function of junction size and observed conductance changes of up to two orders of magnitude as junctions were compressed and stretched. Localised interactions between weakly coordinating thienyl sulfurs and the electrodes are responsible for the observed effect and allow reversible monodentate⇄bidentate contact transitions as the junction is modulated in size. We observed an up to ≈100‐fold sensitivity boost of the (methylthio)thiophene‐terminated molecular wire compared with its non‐hemilabile (methylthio)benzene counterpart and demonstrate a previously unexplored application of hemilabile ligands to molecular electronics.</jats:p>

Item Type: Article
Depositing User: Symplectic Admin
Date Deposited: 30 Jan 2020 15:18
Last Modified: 05 Sep 2023 00:33
DOI: 10.1002/ange.201906400
Open Access URL: https://doi.org/10.1002/ange.201906400
Related URLs:
URI: https://livrepository.liverpool.ac.uk/id/eprint/3072716