Egleston, Benjamin D ORCID: 0000-0003-2125-6569, Luzyanin, Konstantin V ORCID: 0000-0001-9312-7139, Brand, Michael C ORCID: 0000-0002-4556-5609, Clowes, Rob, Briggs, Michael E ORCID: 0000-0003-1474-1267, Greenaway, Rebecca L ORCID: 0000-0003-1541-4399 and Cooper, Andrew I ORCID: 0000-0003-0201-1021
(2020)
Controlling Gas Selectivity in Molecular Porous Liquids by Tuning the Cage Window Size.
Angewandte Chemie, 132 (19).
pp. 7432-7436.
Text
Gas Selectivity in PLs.docx - Author Accepted Manuscript Download (1MB) |
Abstract
<jats:title>Abstract</jats:title><jats:p>Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe‐selective to CH<jats:sub>4</jats:sub>‐selective, which is understood using <jats:sup>129</jats:sup>Xe, <jats:sup>1</jats:sup>H, and pulsed‐field gradient NMR spectroscopy.</jats:p>
Item Type: | Article |
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Depositing User: | Symplectic Admin |
Date Deposited: | 11 Jun 2020 08:44 |
Last Modified: | 18 Sep 2023 18:57 |
DOI: | 10.1002/ange.201914037 |
Related URLs: | |
URI: | https://livrepository.liverpool.ac.uk/id/eprint/3090052 |