Chen, Zhenyu ORCID: 0000-0001-7714-9936, Chen, Guanhong, Aboo, Ahmed H, Iggo, Jonathan ORCID: 0000-0001-8070-1226 and Xiao, Jianliang ORCID: 0000-0003-2010-247X
(2020)
Methanol as Hydrogen Source: Transfer Hydrogenation of Aldehydes near Room Temperature.
Asian Journal of Organic Chemistry, 9 (8).
pp. 1174-1178.
Text
Manuscript.pdf - Author Accepted Manuscript Download (697kB) | Preview |
Abstract
<jats:title>Abstract</jats:title><jats:p>A cyclometalated rhodium complex has been found to show excellent activity in dehydrogenation of methanol at room temperature. This feature allows for the catalytic transfer hydrogenation of various aldehydes with methanol as both hydrogen source and solvent under very mild conditions. A hydroxy functionality on the ligand is shown to be critical for this unusual activity.</jats:p>
Item Type: | Article |
---|---|
Uncontrolled Keywords: | transfer hydrogenation, aldehydes, methanol, rhodium complex, room temperature |
Depositing User: | Symplectic Admin |
Date Deposited: | 07 Sep 2020 09:17 |
Last Modified: | 18 Sep 2023 19:20 |
DOI: | 10.1002/ajoc.202000241 |
Related URLs: | |
URI: | https://livrepository.liverpool.ac.uk/id/eprint/3099949 |