Butler, Ian R, Beaumont, Michael, Bruce, Michael I, Zaitseva, Natalia N, Iggo, Jonathan A ORCID: 0000-0001-8070-1226, Robertson, Craig ORCID: 0000-0002-4789-7607, Horton, Peter N and Coles, Simon J
(2021)
Synthesis and Structures of 1,1′,2-Tribromoferrocene, 1,1′,2,2′-Tetrabromoferrocene, 1,1′,2,2′-Tetrabromoruthenocene: Expanding the Range of Precursors for the Metallocene Chemist.
Australian Journal of Chemistry, 74 (3).
pp. 204-210.
Text
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Abstract
<jats:p> The synthesis, characterisation, and isolation of 1,1′,2-tribromoferrocene and 1,1′,2,2′-tetrabromoferrocene, which are key synthons in ferrocene chemistry, are described. These compounds are prepared using α-halide assisted lithiation. The crystal structures of 1,1′,2-tribromoferrocene, 1,1′,2,2′-tetrabromoferrocene, 1,1′-dibromoruthenocene, and 1,1′,2,2′-tetrabromoruthenocene have been determined and are reported together with a brief discussion of the intramolecular forces involved in the crystal structures. </jats:p>
Item Type: | Article |
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Depositing User: | Symplectic Admin |
Date Deposited: | 16 Nov 2020 09:51 |
Last Modified: | 18 Jan 2023 23:21 |
DOI: | 10.1071/ch19184 |
Related URLs: | |
URI: | https://livrepository.liverpool.ac.uk/id/eprint/3107060 |