Facile gas-phase hydrodeoxygenation of 2,5-dimethylfuran over bifunctional metal-acid catalyst Pt-Cs<sub>2.5</sub>H<sub>0.5</sub>PW<sub>12</sub>O<sub>40</sub>


Althikrallah, Hanan, Kozhevnikova, Elena F ORCID: 0000-0001-8242-7945 and Kozhevnikov, Ivan V ORCID: 0000-0003-2453-5256 (2021) Facile gas-phase hydrodeoxygenation of 2,5-dimethylfuran over bifunctional metal-acid catalyst Pt-Cs<sub>2.5</sub>H<sub>0.5</sub>PW<sub>12</sub>O<sub>40</sub>. CHEMICAL COMMUNICATIONS, 57 (2). pp. 227-230. ISSN 1359-7345, 1364-548X

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Abstract

2,5-Dimethylfuran is deoxygenated to n-hexane with 100% yield on a bifunctional Pt/C-Cs<sub>2.5</sub>H<sub>0.5</sub>PW<sub>12</sub>O<sub>40</sub> catalyst under very mild conditions (90 °C, 1 bar H<sub>2</sub>) in a one-step gas-phase process. A proposed mechanism includes a sequence of hydrogenolysis, hydrogenation and dehydration steps occurring on Pt and proton sites of the bifunctional catalyst.

Item Type: Article
Uncontrolled Keywords: 3405 Organic Chemistry, 34 Chemical Sciences
Depositing User: Symplectic Admin
Date Deposited: 18 Dec 2020 13:56
Last Modified: 07 Dec 2024 11:17
DOI: 10.1039/d0cc06934e
Related URLs:
URI: https://livrepository.liverpool.ac.uk/id/eprint/3110788
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