Jie, Kecheng, Zhou, Yujuan, Li, Errui, Zhao, Run, Liu, Ming ORCID: 0000-0003-0008-1480 and Huang, Feihe
(2018)
Linear Positional Isomer Sorting in Nonporous Adaptive Crystals of a Pillar[5]arene.
Journal of the American Chemical Society, 140 (9).
pp. 3190-3193.
Text
P5-Position Isomer-FH20171213.doc - Author Accepted Manuscript Download (4MB) |
Abstract
Here we show a new adsorptive separation approach using nonporous adaptive crystals of a pillar[5]arene. Desolvated perethylated pillar[5]arene crystals (EtP5α) with a nonporous character selectively adsorb 1-pentene (1-Pe) over its positional isomer 2-pentene (2-Pe), leading to a structural change from EtP5α to 1-Pe loaded structure (1-Pe@EtP5). The purity of 1-Pe reaches 98.7% in just one cycle and EtP5α can be reused without losing separation performance.
Item Type: | Article |
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Depositing User: | Symplectic Admin |
Date Deposited: | 13 Jan 2021 12:10 |
Last Modified: | 18 Jan 2023 23:05 |
DOI: | 10.1021/jacs.7b13156 |
Related URLs: | |
URI: | https://livrepository.liverpool.ac.uk/id/eprint/3111711 |