Ion shuttling between emulsion droplets by crown ether modified gold nanoparticles


Kunstmann-Olsen, Casper, Belic, Domagoj ORCID: 0000-0002-7954-7046, Bradley, Dan F, Danks, Stephen P, Diaz Fernandez, Yuri A ORCID: 0000-0003-3422-8663, Grzelczak, Marcin P, Hill, Alexander P, Qiao, Xiaohang ORCID: 0000-0001-7801-4603, Raval, Rasmita, Sorzabal-Bellido, Ioritz ORCID: 0000-0001-8050-1443 et al (show 1 more authors) (2021) Ion shuttling between emulsion droplets by crown ether modified gold nanoparticles. Nanoscale Advances, 3 (11). pp. 3136-3144. ISSN 2516-0230, 2516-0230

Access the full-text of this item by clicking on the Open Access link.

Abstract

Selective unidirectional transport of barium ions between droplets in a water-in-chloroform emulsion is demonstrated. Gold nanoparticles (GNPs) modified with a thiolated crown ether act as barium ion complexing shuttles that carry the ions from one population of droplets (<i>source</i>) to another (<i>target</i>). This process is driven by a steep barium ion concentration gradient between <i>source</i> and <i>target</i> droplets. The concentration of barium ions in the target droplets is kept low at all times by the precipitation of insoluble barium sulfate. A potential role of electrostatically coupled secondary processes that maintain the electroneutrality of the emulsion droplets is discussed. Charging of the GNP metal cores by electron transfer in the presence of the Fe(ii)/Fe(iii) redox couple appears to affect the partitioning of the GNPs between the water droplets and the chloroform phase. Processes have been monitored and studied by optical microscopy, Raman spectroscopy, cryogenic scanning electron microscopy (cryo-SEM) and zeta potential. The shuttle action of the GNPs has further been demonstrated electrochemically in a model system.

Item Type: Article
Uncontrolled Keywords: 34 Chemical Sciences, 3406 Physical Chemistry, Bioengineering
Divisions: Faculty of Science and Engineering > IDEAS
Faculty of Science and Engineering > School of Physical Sciences
Depositing User: Symplectic Admin
Date Deposited: 12 May 2021 09:20
Last Modified: 14 Aug 2025 19:55
DOI: 10.1039/d1na00009h
Open Access URL: https://doi.org/10.1039/D1NA00009H
Related Websites:
URI: https://livrepository.liverpool.ac.uk/id/eprint/3122433
Altmetric
CORE (COnnecting REpositories)