Creating porosity in a trianglimine macrocycle by heterochiral pairing



He, Donglin, Clowes, Rob, Little, Marc A, Liu, Ming and Cooper, Andrew I
(2021) Creating porosity in a trianglimine macrocycle by heterochiral pairing. CHEMICAL COMMUNICATIONS, 57 (50). pp. 6141-6144.

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Abstract

Macrocycles are usually non-porous or barely porous in the solid-state because of their small intrinsic cavity sizes and tendency to close-pack. Here, we use a heterochiral pairing strategy to introduce porosity in a trianglimine macrocycle, by co-crystallising two macrocycles with opposing chiralities. The stable racemic trianglimine crystal contains an interconnected pore network that has a Brunauer-Emmett-Teller (BET) surface area of 355 m2 g-1.

Item Type: Article
Uncontrolled Keywords: 3402 Inorganic Chemistry, 34 Chemical Sciences
Divisions: Faculty of Science and Engineering > School of Physical Sciences
Depositing User: Symplectic Admin
Date Deposited: 02 Jun 2021 14:50
Last Modified: 22 Jun 2024 14:15
DOI: 10.1039/d1cc01650d
Related URLs:
URI: https://livrepository.liverpool.ac.uk/id/eprint/3124902