The Complex Role of Aluminium Contamination in Nickel-rich Layered Oxide Cathodes for Lithium-ion Batteries

Lee, Juhan ORCID: 0000-0001-5036-3449, Amari, Houari, Bahri, Mounib ORCID: 0000-0002-8336-9158, Shen, Zonghao, Xu, Chao, Ruff, Zachary, Grey, Clare, Ersen, Ovidiu, Aguadero, Ainara, Browning, Nigel ORCID: 0000-0003-0491-251X
et al (show 1 more authors) (2021) The Complex Role of Aluminium Contamination in Nickel-rich Layered Oxide Cathodes for Lithium-ion Batteries. Batteries & Supercaps, 4 (12). pp. 1813-1820.

[img] Text
Accepted Article.pdf - Author Accepted Manuscript

Download (1MB) | Preview


<jats:title>Abstract</jats:title><jats:p>A major challenge for lithium‐ion batteries based on nickel‐rich layered oxide cathodes is capacity fading. While chemo‐mechanical degradation and/or structural transformation are widely considered responsible for degradation, a comprehensive understanding of this process is still not complete. For the stable performance of these cathode materials, aluminium (Al) plays a crucial role, not only as a current collector but also as substitutional element for the transition metals in the cathodes and a protective oxide coating (as Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>). However, excess Al can be detrimental due to both its redox inactive nature in the cathode and the insulating nature of Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>. In this work, we report an analysis of the Al content in two different types of nickel‐rich manganese cobalt oxide cathode materials after battery cycling. Our results indicate a significant thickening of Al‐containing phases on the surface of the NMC811 electrode. Similar results are observed from commercial batteries (a mixture of NMC532 and LiMn<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub>) that were analysed before use and at the end of life, where Al‐containing phases were found to increase significantly at surfaces and grain boundaries. Considering the detrimental effects of the excess Al in the nickel‐rich cathodes, our observation of increased Al content via battery cycling is believed to bring a new perspective to the ongoing discussions regarding the capacity fading phenomenon of nickel‐rich layered oxide materials as part of their complex degradation mechanisms.</jats:p>

Item Type: Article
Uncontrolled Keywords: aluminium coating, Li-ion batteries, layered oxides, NMC811, Ni-rich cathodes
Divisions: Faculty of Science and Engineering > School of Engineering
Depositing User: Symplectic Admin
Date Deposited: 16 Jun 2021 09:03
Last Modified: 05 Sep 2023 13:26
DOI: 10.1002/batt.202100110
Related URLs: